Home > Faculty (by Name | by Area | by Title ) > Paul Ziemann
Paul J. Ziemann
Professor of Atmospheric Chemistry
Academic Degrees:
Specialization:
- Our research involves experimental studies of the chemistry of submicron atmospheric aerosol particles. Particles in this small size range are generally formed by combustion or by a process referred to as gas-to-particle conversion, which is often quite complex and can include photochemical gas-phase reactions, heterogeneous surface chemistry, homogeneous nucleation, and liquid-phase reactions. The resulting particles play important roles in global climate, urban smog formation, visibility, and human health. In our research, we use a thermal desorption particle beam mass spectrometer we developed, in conjunction with standard tools for aerosol sampling and size and composition analysis, such as cascade impactors, differential mobility analysis, and gas chromatography-mass spectrometry, to investigate fundamental processes responsible for gas-to-particle conversion in the atmosphere. In particular, our work is aimed at elucidating the mechanisms by which volatile anthropogenic and biogenic organic compounds are oxidized to form condensable compounds that form particulate material. Information on the products and mechanisms of reactions of gaseous and condensed-phase species, as well as compound thermochemical properties such as vapor pressure are obtained from environmental chamber studies. These tools are also being used in studies of particle formation in combustion systems, such as diesel engines, and for analysis of ambient atmospheric particles. The results of these studies are used to further our understanding of atmospheric aerosol chemistry and the impact of human activities on the atmospheric environment.
Research Group:
Representative Publications:
- Gong, H., Matsunaga, A., and P. J. Ziemann. Products and mechanism of secondary organic aerosol formation from reactions of linear alkenes with NO3 radicals, J. Phys. Chem. A 109: 4312-4324 (2005)
- Docherty, K. S., W. Wu, Y. B. Lim, and P. J. Ziemann. Contributions of organic peroxides to secondary aerosol formed from reactions of monoterpenes with O3, Environ. Sci. Technol. 39: 4049-4059 (2005)
- Chattopadhyay, S., and P. J. Ziemann. Vapor pressures of unsubstituted and substituted monocarboxylic and dicarboxylic acids measured using an improved thermal desorption particle beam mass spectrometry method, Aerosol Sci. Technol. 39:1085-1100 (2005)
- Lim, Y. B., and P. J. Ziemann. Products and mechanism of secondary organic aerosol formation from reactions of linear alkanes with OH radicals in the presence of Nox, Environ. Sci. Technol. 39: 9229-9236 (2005)
- Docherty, K. S., and P. J. Ziemann. Reaction of oleic acid particles with NO3 radicals: products, mechanism, and implications for radical-initiated organic aerosol oxidation, J. Phys. Chem. A 110: 3567-3577 (2006)
Courses Taught:
- Chemistry and Physics of Aerosols
- Chemistry of Natural Waters
Graduate Program Affiliations and Research Focus Areas:
Honors and Awards
- 2001 Kenneth T. Whitby Award, American Association for Aerosol Research
Links:
Address:
- Air Pollution Research Center
- University of California, Riverside
- Riverside, CA 92521
Fax:
© 2008, Regents of the University of California.
